Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes.
نویسندگان
چکیده
Carbon-heteroatom bond formation from copper(III) is commonly invoked as a key step in catalytic reactions, including the century-old Ullmann reactions. Well-defined examples of such reactions have never been observed. Here, we demonstrate that a well-defined Cu(III)-aryl species reacts with a variety nitrogen nucleophiles to undergo facile carbon-nitrogen bond formation.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 130 29 شماره
صفحات -
تاریخ انتشار 2008